TXRF analysis of soils and sediments to assess environmental contamination

Total reflection x-ray fluorescence spectroscopy (TXRF) is proposed for the elemental chemical analysis of crustal environmental samples, such as sediments and soils. A comparative study of TXRF with respect to flame atomic absorption spectroscopy and inductively coupled plasma optical emission spectroscopy was performed. Microwave acid digestion and suspension preparation methods are evaluated. A good agreement was found among the results obtained with different spectroscopic techniques and sample preparation methods for Cr, Mn, Fe, Ni, Cu, and Zn. We demonstrated that TXRF is suitable for the assessment of environmental contamination phenomena, even if the errors for Pb, As, V, and Ba are ingent.     

Analysis of Key Features of Non-Linear Behaviour Using Recurrence Quantification. Case Study: Urban Airborne Pollution at Mexico City

The use of recurrence plots have been extensively used in various fields. In this work, recurrence plots investigate the changes in the non-linear behaviour of urban air pollution using large datasets of raw data (hourly). This analysis has not been used before to extract information from large datasets for this type of non-linear problem. Two different approaches have been used to tackle this problem. The first approach is to show results according to monitoring network. The second approach is to show the results by particle type. This analysis shows the feasibility of using recurrence analysis for pollution monitoring and control.     

Electrochemical advanced oxidation processes: today and tomorrow. A review

In recent years, new advanced oxidation processes based on the electrochemical technology, the so-called electrochemical advanced oxidation processes (EAOPs), have been developed for the prevention and remediation of environmental pollution, especially focusing on water streams. These methods are based on the electrochemical generation of a very powerful oxidizing agent, such as the hydroxyl radical (^?OH) in solution, which is then able to destroy organics up to their mineralization. EAOPs include heterogeneous processes like anodic oxidation and photoelectrocatalysis methods, in which ^?OH are generated at the anode surface either electrochemically or photochemically, and homogeneous processes like electro-Fenton, photoelectro-Fenton, and sonoelectrolysis, in which ^?OH are produced in the bulk solution. This paper presents a general overview of the application of EAOPs on the removal of aqueous organic pollutants, first reviewing the most recent works and then looking to the future. A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed.     

E-bikers’ braking behavior: Results from a naturalistic cycling study

Abstract

Objective: The number of e-bike users has increased significantly over the past few years and with it the associated safety concerns. Because e-bikes are faster than conventional bicycles and more prone to be in conflict with road users, e-bikers may need to perform avoidance maneuvers more frequently. Braking is the most common avoidance maneuver but is also a complex and critical task in emergency situations, because cyclists must reduce speed quickly without losing balance. The aim of this study is to understand the braking strategies of e-bikers in real-world traffic environments and to assess their road safety implications. This article investigates (1) how cyclists on e-bikes use front and rear brakes during routine cycling and (2) whether this behavior changes during unexpected conflicts with other road users.

Methods: Naturalistic data were collected from 6 regular bicycle riders who each rode e-bikes during a period of 2 weeks, for a total of 32.5?h of data. Braking events were identified and characterized through a combined analysis of brake pressure at each wheel, velocity, and longitudinal acceleration. Furthermore, the braking patterns obtained during unexpected events were compared with braking patterns during routine cycling.

Results: In the majority of braking events during routine cycling, cyclists used only one brake at a time, favoring one of the 2 brakes according to a personal pre-established pattern. However, the favored brake varied among cyclists: 66% favored the rear brake and 16% the front brake. Only 16% of the cyclists showed no clear preference, variously using rear brake, front brake, or combined braking (both brakes at the same time), suggesting that the selection of which brake to use depended on the characteristics of the specific scenario experienced by the cyclist rather than on a personal preference. In unexpected conflicts, generally requiring a larger deceleration, combined braking became more prevalent for most of the cyclists; still, when combined braking was not applied, cyclists continued to use the favored brake of routine cycling. Kinematic analysis revealed that, when larger decelerations were required, cyclists more frequently used combined braking instead of single braking.

Conclusions: The results provide new insights into the behavior of cyclists on e-bikes and may provide support in the development of safety measures including guidelines and best practices for optimal brake use. The results may also inform the design of braking systems intended to reduce the complexity of the braking operation.     

Environmental and economic sustainability in public contexts: the impact of hand-drying options on waste management,carbon emissions and operating costs

Environment, Development and Sustainability - Due to the high density of users hosted everyday, public buildings are important producers of waste and emissions of greenhouse gases (GHGs). Public...     

Chemical characterization and toxicity assessment for the sustainable management of end of life cathode ray tubes

Journal of Material Cycles and Waste Management - Cathode ray tube (CRT) monitors represent currently one of the most produced category of electronic waste. In CRTs most of the glass components...     

Synoptic patterns associated with extreme dust events in the Mediterranean Basin

Extreme dust events over the western, central and eastern Mediterranean are identified analysing the aerosol optical depth remote-sensed by the Moderate Resolution Imaging Spectroradiometer (MODIS) in 2001–2010 and simulated by the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model in 2000–2007. The seasonal variability of the dust events and the evolution of the synoptic circulation patterns before and during the events are studied. Results show that the highest occurrence of short events (1–3 days) is in the eastern Mediterranean, while long events (more than 4 days) are more frequent in the western Mediterranean. Short events are concentrated in spring, while long events do not show a clear seasonality. The synoptic circulation patterns accompanying short and long events are similar, and the occurrence across the Mediterranean Basin is related to westerly low-pressure systems. Dust events in the western Mediterranean are associated with high-pressure conditions limiting the development of lows to the western North Africa, while the eastward evolution of cyclones over the central Mediterranean and Northern Africa accompanies dust events in the central and eastern Mediterranean.     

Selective collection as a pretreatment for indirect solid recovered fuel generation

Effective selective collection (SC) has been increasing in many countries of the European Union. As a consequence the composition of residual municipal solid waste (RMSW) is changing not only because of economic development, but also due to the collection system. The input of RMSW treatment plants is thus not homogeneous. This paper analyses two case studies involving a total of five SC scenarios and their impact on the generation of solid recovered fuel (SRF) with/without bio-drying, post-treatment and packaging take back programs (TBPs). These case studies are based on two types of SC: kerbside and drop-off. The latest regulation on SRF classification is taken into account: energy content, Cl and Hg concentrations are assessed and discussed. The role of the respirometric index (RI) is also analyzed. Results show that when SC is highly efficient RMSW can be classified directly as SRF, but only if the introduction of RI does not set stringent respirometric targets. The role of packaging TBPs is important as the residual waste remaining after the packaging has been processed, can be valorized increasing the lower heating value (LHV) of the residual RMSW and minimizing the streams that should be landfilled. The source separation of food waste has a significant impact on the suitability of bio-drying: when the SC of food waste is very efficient, its percentage in the RMSW may be too low for effective bio-drying.